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排序方式: 共有152条查询结果,搜索用时 16 毫秒
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Ali Atif Mossad Ghazwani Nimah Asaad Algarni H. Ismail Adel A. 《Research on Chemical Intermediates》2019,45(5):3089-3106
Research on Chemical Intermediates - Zinc oxide-doped tin dioxide (ZnO–SnO2) nanomaterials were prepared by a sol–gel method with and without different amounts (0.5, 1.0 and... 相似文献
34.
The carbon-supported cobalt(III) complex of β-pyrrole-brominated 5,10,15-tris(pentafluorophenyl)corrole [Co(tpfc)Br(8)/C] is introduced as a nonplatinum alternative for electrocatalytic oxygen reduction in aqueous solutions. Through systematic work, the basic kinetic parameters of this reaction were studied, using rotating ring disk electrode electrochemical methods in the pH range of 0-11. Pronounced catalytic activity was detected in acid solutions along with shifts of the Co(II)/Co(III) and O(2) redox couples to more positive values (onset of 0.56 V at pH 0). A series of independent measurements have been used to prove that the dominant mechanism for oxygen reduction by Co(tpfc)Br(8)/C catalysis is the direct four-electron pathway to water. 相似文献
35.
This study describes the electrochemical, in situ spectroelectrochemical, in situ electrocolorimetric and electrocatalytic characterization of metallophthalocyanines bearing four dioctylaminocarbonyl biphenyloxy groups (MPc's). While CoPc gives both metal‐based and ring‐based redox processes, ZnPc and CuPc show only ring‐based reduction and oxidation processes. In‐situ electrocolorimetric method was applied to investigate color of the electrogenerated anionic and cationic forms of the complexes. Perchloric acid titrations monitored by cyclic voltammetry and spectrophotometry represent possible electrocatalytic activities of the complexes for hydrogen evolution reaction. CuPc having inactive metal center incorporated into a Nafion film on GCE decreases overpotential of the electrode for H+ reduction in aqueous solution. 相似文献
36.
Muhammad Imran Fayyaz Hussain Sardar Sikandar Hayat Rana Muhammad Arif Khalil Tariq Munir Muhammad Atif Sattar Abdul Rehman Muhammad Arshad Javid Sheikh Aftab Ahmad 《Surface and interface analysis : SIA》2019,51(5):489-497
This study presents the diffusion of heterogeneous ternary (Cu-Ag-Zr) adatoms clusters on Ag(111) using molecular dynamics techniques which could be important for the surface phenomena's and helpful for the ternary cluster's growth and formation of ternary alloy-based thin films. The mechanism of nanoscale surface diffusion is investigated for 1Cu-1Ag-1Zr, 2Cu-2Ag-2Zr, 3Cu-3Ag-3Zr, and 4Cu-4Ag-4Zr clusters at temperatures 300, 500, and 700 K. The diffusion mechanism displays that the diffusion of trimer cluster exhibits hopping, sliding, and shearing at 300 K, whereas for hexamer, nonamer, and decamer, the diffusion rate is low; however, breathing, anchoring, and concentrated motion dominates. At 500 K, trimer and hexamer show the process of atomic exchange; however, the atomic exchange is not observed in the case of nonamer and decamer diffusion. The atomic exchange mechanism of Cu and Zr adatoms dominates at 700 K for all size clusters, except Ag adatoms, where Zr adatoms show a relatively more tendency. Separation and rejoining of the one and two adatoms (likely Zr adatom) are also witnessed at high temperature. The pop-up of Ag adatoms also occurs in very short intervals over the remaining adatoms of clusters. Interestingly, during trimer diffusion, the adsorption of the Zr- or Cu-adatom among the trimer cluster into the substitutional site is found. At 700 K, vacancy generation, filling of vacancies, and migration of vacancy, in the neighborhood of the adatoms cluster, also observed. Moreover, the rate of diffusion decreases with the size increase of the clusters and increases with the increase in temperature. 相似文献
37.
S. T. Tasnuva U. A. Qamar Kashif Ghafoor F. Sahena M. H. A. Jahurul A. H. Rukshana 《Natural product research》2019,33(10):1495-1499
The aim of the study was to isolate digestive enzymes inhibitors from Mimosa pudica through a bioassay-guided fractionation approach. Repeated silica gel and sephadex LH 20 column chromatographies of bioactive fractions afforded stigmasterol, quercetin and avicularin as digestive enzymes inhibitors whose IC50 values as compared to acarbose (351.02 ± 1.46 μg mL?1) were found to be as 91.08 ± 1.54, 75.16 ± 0.92 and 481.7 ± 0.703 μg mL?1, respectively. In conclusion, M. pudica could be a good and safe source of digestive enzymes inhibitors for the management of diabetes in future. 相似文献
38.
Ikram Hussain Atif Fazal Khurshid Alam Anwar Hossaen 《Polymer Degradation and Stability》2010,95(12):2289-2299
Catalyst creates new grades of polyethylenes while their degradation phenomena determine the resulting application profiles. The resins and the end-products eventually contain residual catalysts. Therefore, the effects of the following two residual catalysts—one Ziegler-Natta [PQ Silica/Bu2Mg/tBuCl/TiCl4], and the other metallocene [PQ Silica/MAO/(nBuCp)2ZrCl2]—on the UV-induced degradation of the resulting unstabilized ethylene homopolymer films were studied. The MetCat HomoPE film was found to be more susceptible to UV-induced degradation degradation than the Z-N HomoPE one despite the residual Zr level was 1/15th of the Ti content. Therefore, the zirconocene residual catalyst better (i) facilitated the UV-initiated reaction, and (ii) decreased the activation energy required for the decomposition of the resulting hydroperoxide. These findings were explained from the differences in (i) electronic configuration and atomic radius, and (ii) surface chemistry and solid-state electronic environment of these catalyst systems. In both films, Tpm and Tpc did not significantly vary with the exposure time. The change of % crystallinity showed to be irregular and disturbed. As a function of carbonyl index, Tpm and Tpc,varied in a similar fashion in the MetCat HomoPE film. However, they significantly differed for the Z-N HomoPE film. Here, Tpm did not appreciably change whereas Tpc initially increased very mildly; then it did not essentially differ. 相似文献
39.
We report a two dimensional Stokes vector imaging technique for transamination measurements of the polarization state of scattering
medium. Measurement of the depth resolved Stokes parameters allows determination of the degree of polarization, birefringence,
retardation, optical activity and characterization of the medium. The polarized light preserved and degree of polarization
very with scatterer concentration. The transmitted intensity patterns by varying a polarization state of the incident laser
light (λ = 632.8 nm) and changing analyzer configuration provides a useful information about concentration, orientation, and
shape of the sample under investigation. The results are important for the understanding of polarization phenomenon in turbid
media, like biological tissues. 相似文献
40.
Anis Fadhlina Izyani Awang Qamar Uddin Ahmed Syed Adnan Ali Shah Juliana Md. Jaffri Kashif Ghafoor A. B. M. Helal Uddin 《Natural product research》2020,34(5):629-637
AbstractStereospermum fimbriatum or locally known as “Chicha” is traditionally used for itchy skin, earache, stomachache and postpartum treatments. This study was designed to evaluate the antimicrobial potential of S. fimbriatum’s stem bark against 11 pathogens and isolate its bioactive compound. Successive soxhlet extraction was conducted using n-hexane, dichloromethane (DCM) and methanol. Disc diffusion, minimum inhibitory and bactericidal concentration (MIC & MBC) assays were done to examine the antimicrobial activity. Bioassay-guided isolation was conducted on S. fimbriatum’s extract. The DCM extract of stem bark (DS) was the most potent extract followed by n-hexane extract of the stem bark (NS). A novel compound was isolated and coded as C1 which demonstrated potent antibacterial effects with the MIC values as low as 3.13?µg/mL to 6.25?µg/mL, against S. epidermidis, MRSA and S. aureus. Thus, S. fimbriatum could be a potential source of antimicrobial agents for the treatment of skin infections, specifically, MRSA. 相似文献